Room-Temperature Fluorohydrogenate Ionic Liquids of Alkylpyridinium Cations and Allylated Quarternary Cyclic Ammonium Cations
نویسندگان
چکیده
منابع مشابه
The influence of lithium cations on dynamics and structure of room temperature ionic liquids.
The orientational relaxation dynamics of perylene in the room temperature ionic liquid (RTIL) 1-butyl-3-methylimidazolium bis(trifluoromethyl)sulfonyl imide were studied as a function of lithium ion concentration. Perylene is nonpolar and locates in the alkyl regions of the RTIL. The lithium cation was added as lithium bis(trifluoromethyl)sulfonyl imide, so the addition of Li(+) did not change ...
متن کاملRoom Temperature Ionic Liquids
The initial objective of this project was to carry out a fundamental study of the transport characteristics of a variety of gases and organic solutes in room temperature ionic liquids. The goal was to combine information collected from a number of different experimental measurements in order to develop a fundamental understanding of the interactions governing transport in ionic liquids. Measure...
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Novel protic ionic liquids (PILs) based on a tributyl phosphonium cation have been synthesised and characterised, revealing that the phosphonium based ILs show high thermal stability, high ionic conductivity and facile proton reduction compared to the corresponding ammonium based ILs.
متن کاملπ+-π+ stacking of imidazolium cations enhances molecular layering of room temperature ionic liquids at their interfaces.
The interfacial structure of room temperature ionic liquids (RTILs) controls many of the unique properties of RTILs, such as the high capacitance of RTILs and the efficiency of charge transport between RTILs and electrodes. RTILs have been experimentally shown to exhibit interfacial molecular layering structures over a 10 Å length scale. However, the driving force behind the formation of these ...
متن کاملElectrochemical Applications of Room - Temperature Ionic Liquids
R3 R2 There is good evidence that the first room-temperature ionic liquid or RTIL was identified and characterized by Walden in 1914, who examined the electrical conductivity of ethylammonium nitrate.1 Thus, it would not be an exaggeration to say that the very beginnings of electrochemistry involved room-temperature ionic liquids! Although once considered to be a curious subset of the general c...
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ژورنال
عنوان ژورنال: Electrochemical and Solid-State Letters
سال: 2009
ISSN: 1099-0062
DOI: 10.1149/1.3117215